Hydrothermal synthesis,crystal structures,and photoluminescent properties of two cadmium(II) coordination polymers derived from dicarboxylates and N-donor ligands |
| |
Abstract: | Two metal coordination polymers, [Cd(ipa)(L1)(H2O)]n (1) and [Cd(ipa)(L2)]n (2) [H2ipa?=?isophthalic acid, L1?=?3,5-bis(imidazole-1-yl)pyridine and L2?=?3,5-bis(benzoimidazo-1-ly)pyridine], have been synthesized and structurally characterized by IR, elemental analysis, XRD, and X-ray single-crystal diffraction. Complex 1 shows a twofold cds topological net and 2 features a 3-D pcu topological net. Luminescent properties of 1 and 2 were investigated in the solid state at room temperature. |
| |
Keywords: | Cd coordination polymers Crystal structures Luminescent properties |
|
|