Synthesis,crystal structure,and photoluminescence of a new Zn(II) molecular box compound derived from a two-armed bis-terdendate ligand |
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| Abstract: | The dinuclear compound Zn2(HL2)2(ClO4)2(C2H5OH)0.5(H2O)2 (1) based on di(2-acetylpyridyl)-6,6′-dicarboxylic acid hydrazone-2,2′-bipyridine (H2L2) has been obtained via self-assembly. X-ray crystallography indicated the formation of a molecular box rather than a helicate. The photoluminescence properties of 1 in the solid state have an emission at ca 500 nm with excitation at 400 nm at room temperature. |
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| Keywords: | Molecular box Self-assembly Photoluminescence |
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