The Synthesis,Crystal, Molecular and Electronic Structure of [ReCl2(NO)(py)3] |
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Abstract: | In line with our investigations of rhenium nitrosyl complexes, we have studied the reaction of [ReCl3(NO)(OPPh3)(PPh3)] with pyridine. The [ReCl2(NO)(py)3] complex obtained in this reaction has been characterised by IR, electronic spectra and magnetochemical measurements; ligand field parameters and the electronic structure have been determined. The crystal and molecular structure of [ReCl2(NO)(py)3] has been solved by the heavy atom method. Crystals of [ReCl2(NO)(py)3] contain distorted octahedral molecules with the pyridine ligands in the mer-arrangement. The nitrosyl group is coordinated linearly to the rhenium atom as NO+. |
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Keywords: | Rhenium Complexes Nitrosyl X-ray Structure Electronic Structure Nitric Oxide |
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