Rhenium(VII) polyhydrides supported by chelating bis -phosphine ligands: DPEphos,xantphos and biphep期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Rhenium(VII) polyhydrides supported by chelating bis -phosphine ligands: DPEphos,xantphos and biphep

Abstract:	Three new rhenium polyhydride complexes, [ReH₇(L₂)], incorporating bidentate organophosphorus ligands (L₂ = DPEphos, xantphos and biphep), were successfully synthesized using the corresponding [ReOCl₃(L₂)] complexes as precursors. The polyhydride complexes were characterized by IR, ¹H and ³¹P NMR, and elemental analysis.

Keywords:	Rhenium Polyhydrides Synthesis Large bite-angle phosphines