Synthesis,crystal structure and magnetic property of a maleonitriledithiolate nickel(III) complex containing an ammonium crown ether cation |
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| Abstract: | The synthesis, molecular structure and spectroscopic and magnetic properties of (NH4)2(15-crown-5)3Ni(mnt)2]2 (mnt?=?maleonitriledithiolate dianion) are reported. The most notable structural feature of (NH4)2(15-crown-5)3Ni(mnt)2]2 is that the ions form a stacked structure with well-separated columns along the c and a axes. Variable temperature magnetic susceptibility measurements indicate strong antiferromagnetic interactions in the complex. |
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| Keywords: | Maleonitriledithiolate 15-Crown-5 Crystal structure Dimer Nickel(III) complex |
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