Hydrothermal synthesis and crystal structure of two new lanthanide coordination polymers with 1,2-phenylenediacetate |
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Abstract: | Two new compounds {[Ln2(1,2-pda)3(H2O)2]·?2H2O} n (1,2-H2pda?=?1,2-phenylenediacetic acid, Ln?=?Tb, 1; Ho, 2) were prepared by hydrothermal reaction and characterized by X-ray crystallography. The Ln3+ is nine-coordinate by eight oxygen atoms of six 1,2-pda ligands and one oxygen of water. Ln3+ ions are bridged by 1,2-pda ligands via bridging/chelating-bridging pentadentate and chelating-bridging/chelating-bridging hexadentate coordination to form 3-D framework structures. Complex 1 emits strong green fluorescence corresponding to 5D4???7Fj (j?=?6–3) transitions of the Tb3+. |
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Keywords: | Lanthanide coordination polymers 1,2-Phenylenediacetate Hydrothermal synthesis Crystal structure |
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