The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents |
| |
| Authors: | de Greef Tom F A Nieuwenhuizen Marko M L Stals Patrick J M Fitié Carel F C Palmans Anja R A Sijbesma Rint P Meijer E W |
| |
| Affiliation: | Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands. e.w.meijer@tue.nl. |
| |
| Abstract: | Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
