| Intramolecular O-Sn coordination in (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol: Evidence by X-ray diffracation analysis and bromination |
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| 引用本文： | FU,Fang-Xin FU,Yu-Jie ZHU,Dong-Sheng FANG,Qun-Xin PAN,Hua-DeChemistry Department,Northeast Normal University,Changchun,Jilin 130024,ChinaLIN,Yong-Hua JIN,Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences,Changchun,Jilin 130022,China. Intramolecular O-Sn coordination in (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol: Evidence by X-ray diffracation analysis and bromination[J]. 中国化学, 1994, 12(4): 365-371. DOI: 10.1002/cjoc.19940120411 |
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| 作者姓名： | FU Fang-Xin FU Yu-Jie ZHU Dong-Sheng FANG Qun-Xin PAN Hua-DeChemistry Department Northeast Normal University Changchun Jilin 130024 ChinaLIN Yong-Hua JIN Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 China |
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| 作者单位： | FU，Fang-Xin FU，Yu-Jie ZHU，Dong-Sheng FANG，Qun-Xin PAN，Hua-DeChemistry Department，Northeast Normal University，Changchun，Jilin 130024，ChinaLIN，Yong-Hua JIN，Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences，Changchun，Jilin 130022，China |
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| 基金项目： | Project supported by the National Natural Sciences Foundation of China. |
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| 摘 要： | The synthesis and properties of (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol (1) are described. Compound 1 crystallizes from alcohol in the monoclinic space group P21/c with unit-cell dimensions a=9.296(2), 6=14.081(3), c=18.390(5) A,B=97.70(2), V=2385.5(1) A3, Z=4, F(000)=1008, Dc=1.38 g.cm-3,u=10.88 cm-1, final R=0.0359 for 3079 observed reflection [I > 3(I)]. The X-ray diffraction analysis of this compound shows the presence of an intramolecular coordination to the tin atom giving rise to a five-membered ring in which the metal exhibits a distroted trignoal bipyramidal geometry; as a consequence, a phenyl group, probably the apical one, is cleaved more easily by bromine than the vinyl substituent.
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Intramolecular O-Sn coordination in (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol: Evidence by X-ray diffracation analysis and bromination |
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| FU,Fang-Xin FU,Yu-Jie ZHU,Dong-Sheng FANG,Qun-Xin PAN,Hua-DeChemistry Department,Northeast Normal University,Changchun,Jilin ,ChinaLIN,Yong-Hua JIN,Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences,Changchun,Jilin ,China. Intramolecular O-Sn coordination in (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol: Evidence by X-ray diffracation analysis and bromination[J]. Chinese Journal of Chemistry, 1994, 12(4): 365-371. DOI: 10.1002/cjoc.19940120411 |
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| Authors: | FU Fang-Xin FU Yu-Jie ZHU Dong-Sheng FANG Qun-Xin PAN Hua-DeChemistry Department Northeast Normal University Changchun Jilin ChinaLIN Yong-Hua JIN Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin China |
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| Affiliation: | FU,Fang-Xin FU,Yu-Jie ZHU,Dong-Sheng FANG,Qun-Xin PAN,Hua-DeChemistry Department,Northeast Normal University,Changchun,Jilin 130024,ChinaLIN,Yong-Hua JIN,Song-Chun Changchun Institute of Applied Chemistry Chinese Academy of Sciences,Changchun,Jilin 130022,China |
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| Abstract: | The synthesis and properties of (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol (1) are described. Compound 1 crystallizes from alcohol in the monoclinic space group P21/c with unit-cell dimensions a=9.296(2), 6=14.081(3), c=18.390(5) A,B=97.70(2), V=2385.5(1) A3, Z=4, F(000)=1008, Dc=1.38 g.cm-3,u=10.88 cm-1, final R=0.0359 for 3079 observed reflection [I > 3(I)]. The X-ray diffraction analysis of this compound shows the presence of an intramolecular coordination to the tin atom giving rise to a five-membered ring in which the metal exhibits a distroted trignoal bipyramidal geometry; as a consequence, a phenyl group, probably the apical one, is cleaved more easily by bromine than the vinyl substituent. |
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| Keywords: | Sythesis X-ray diffraction analysis (Z)-l-(triphenylstannyl)-3-phenyl-l-buten-3-ol. |
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