Photolysis of vinyl bromides in the presence of tetrabutylammonium azide: trapping of a vinyl cation with azide ion |
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| Authors: | Tsugio Kitamura Shinjiro Kobayashi Hiroshi Taniguchi |
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| Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Kyushu University, Fukuoka 812, Japan |
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| Abstract: | Vinyl cations generated by the title photolysis gave vinyl azides by capture of an azide ion and their further photolyses resulted in the formation of cycloaddition-products via nitrile ylides derived from the corresponding azirines. |
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