Role of hydroxyl groups in the stereochemistry of hydrogen transfer from chiral NAD(P)H model to carbonyl |
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| Authors: | Taketoshi Makino,Tetsuji Nunozawa,Naomichi Baba,Jun&#x ichi Oda,Yuzo Inouye |
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| Affiliation: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan |
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| Abstract: | Asymmetric reduction of α-ketoester with a chiral dihydronicotinamide was significantly affected by chiral aromatic additives, capable of exerting an attractive interaction with dihydropyridine ring, which was further consolidated through with magnesium. |
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