- and -vinyloxyboranes (alkenyl borinates): stereoselective formation and aldol condensation |
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Authors: | Satoru Masamune Sachio Mori David Van Horn Dee W Brooks |
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Institution: | Department of Chemistry, Massachusetts Institute of Technology Cambridgge, Massachusetts 02139 U.S.A. |
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Abstract: | Vinyloxyboranes, intermediates of Hooz' reaction, are almost exclusively -isomers which can be isomerized to the -isomers. Both isomers undergo stereoselective aldol condensations. |
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