Biomimetic reactions of germacrenes |
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Authors: | Masatake Niwa Masanobu Iguchi Shosuke Yamamura |
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Affiliation: | Faculty of Pharmacy, Meijo University, Tenpaku-ku, Nagoya, Japan |
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Abstract: | The biomimetic reactions of epoxygermacrene-D () with basic alumina afforded three new interesting compounds (, , and ), two of which ( and ) have the same carbon skeleton as that of periplanone-A (), a sexual stimulant for the American cockroach. The remaining one () is a bicyclo[3.1.0]hexane derivative, from whch an axisonitrile-3 type compound () has been produced. Finally, preisocalamendiol () was also converted into . |
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