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Stereoselective epoxidation of acyclic allylic alcohols. A correction of our previous work.
Authors:B.E. Rossiter  T.R. Verhoeven  K.B. Sharpless
Affiliation:Department of Chemistry, Stanford University Stanford, California 94305 U.S.A.
Abstract:A reinvestigation of the stereoselectivities for the epoxidation of acyclic allylic alcohols with MCPBA, and with tert-butyl hydroperoxide catalyzed by V+5 and Mo+6 revealed a number of errors in our original work1 which are rectified. Optimum O-C-C=C dihedral angles are proposed.
Keywords:
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