Stereoselective epoxidation of acyclic allylic alcohols. A correction of our previous work. |
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Authors: | B.E. Rossiter T.R. Verhoeven K.B. Sharpless |
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Affiliation: | Department of Chemistry, Stanford University Stanford, California 94305 U.S.A. |
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Abstract: | A reinvestigation of the stereoselectivities for the epoxidation of acyclic allylic alcohols with MCPBA, and with -butyl hydroperoxide catalyzed by V+5 and Mo+6 revealed a number of errors in our original work1 which are rectified. Optimum O-C-C=C dihedral angles are proposed. |
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