Stereoselective addition of singlet oxygen to 8-isopropylidene-tricyclo[3.2.1.02,4]octane derivatives |
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Authors: | Keiji Okada Toshio Mukai |
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Affiliation: | Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980 Japan |
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Abstract: | Singlet oxygen adds stereoselectively to 8-isopropylidenetricyclo[3.2.1.02,4]octane. The π-orbital distortion and the secondary orbital interaction are discussed in order to explain the observed stereoselectivity. |
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