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Alkylation of benzyl,cyclopropylmethyl and allyl acetates with trialkylaluminum. A stereochemical study
Authors:Akira Itoh  Koichiro Oshima  Shizuka Sasaki  Hajime Yamamoto  Tamejiro Hiyama  Hitosi Nozaki
Affiliation:Department of Industrial Chemistry, Faculty of Engineering Kyoto University, Yoshida, Kyoto 606, Japan
Abstract:The title reaction is found synthetically useful and the stereochemical sudy has revealed that carbocationic intermediates are involved in the reaction of endo-2-acetoxy-norcarane, its epimer, and acetates of cis- and trans-carveol with trimethylaluminum.
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