Alkylation of benzyl,cyclopropylmethyl and allyl acetates with trialkylaluminum. A stereochemical study |
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Authors: | Akira Itoh Koichiro Oshima Shizuka Sasaki Hajime Yamamoto Tamejiro Hiyama Hitosi Nozaki |
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Affiliation: | Department of Industrial Chemistry, Faculty of Engineering Kyoto University, Yoshida, Kyoto 606, Japan |
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Abstract: | The title reaction is found synthetically useful and the stereochemical sudy has revealed that carbocationic intermediates are involved in the reaction of endo-2-acetoxy-norcarane, its epimer, and acetates of cis- and trans-carveol with trimethylaluminum. |
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