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Nucleophilic reactions in strongly acidic media. Highly specific homolytic aromatic alkylation and acylation
Authors:Laily Bin Din  Otto Meth-Cohn  Nigel D.A. Walshe
Affiliation:The Ramage Laboratories, Department of Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT, England
Abstract:Under Minisci reaction conditions, nucleophilic carbon free radicals readily substitute ferrocene (as the ferricinium ion) and protonated acetophenone, the latter reaction being highly positionally specific.
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