Nucleophilic reactions in strongly acidic media. Highly specific homolytic aromatic alkylation and acylation |
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Authors: | Laily Bin Din Otto Meth-Cohn Nigel D.A. Walshe |
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Affiliation: | The Ramage Laboratories, Department of Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT, England |
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Abstract: | Under Minisci reaction conditions, nucleophilic carbon free radicals readily substitute ferrocene (as the ferricinium ion) and protonated acetophenone, the latter reaction being highly positionally specific. |
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