Allylic amidation. An investigation of nitrosocarbonylmethane for direct allylic functionalization of olefins |
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Authors: | Gary E. Keck John B. Yates |
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Affiliation: | Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 U.S.A. |
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Abstract: | Nitrosocarbonylmethane reacts with a variety of olefins an ene pathway, yielding N-substituted hydroxamic acid products in a preparatively useful reaction. With unsymmetrical olefins, observed regiochemical preferences can be rationalized by a mechanism involving electrophilic addition of nitrogen to the olefin. |
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