A facile synthesis of strained bridgehead olefins by a gas-phase elimination reaction |
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Authors: | Konrad B. Becker Rudolf W. Pfluger |
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Affiliation: | Institut für Organische Chemie der Universität Basel CH-4056 Basel, Switzerland |
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Abstract: | A synthesis of bicyclo[3.3.1]non-1-ene and of a 10:1 mixture of bicyclo[4.2.1]non-1(8)-ene and bicyclo[4.2.1]non-1(2)-ene by gas-phase pyrolysis of the corresponding bridgehead acetates and chlorides is reported. |
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