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A facile synthesis of strained bridgehead olefins by a gas-phase elimination reaction
Authors:Konrad B. Becker  Rudolf W. Pfluger
Affiliation:Institut für Organische Chemie der Universität Basel CH-4056 Basel, Switzerland
Abstract:A synthesis of bicyclo[3.3.1]non-1-ene 1 and of a 10:1 mixture of bicyclo[4.2.1]non-1(8)-ene 2 and bicyclo[4.2.1]non-1(2)-ene 3 by gas-phase pyrolysis of the corresponding bridgehead acetates and chlorides is reported.
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