New epoxidation reagents derived from alumina and silicon |
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Authors: | J. Rebek R. McCready |
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Affiliation: | Department of Chemistry, University of Pittsburgh, Pittsburgh, Penna. 15260 U.S.A. |
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Abstract: | Hydrogen peroxide or tert butyl hydroperoxide in contact with basic alumina will epoxidize olefins. Triphenylsilyl hydroperoxide behaves similarly to peracids toward olefins, ketones and allylic alcohols. |
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