Polycyclic rearrangements. A novel,carbonium ion mediated,bicyclo (4.2.0) octa-2,4-diene→1,3,5-cyclooctatriene isomerisation in a propellane framework |
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| Authors: | Goverdhan Mehta Vishwakarma Singh A. Srikrishna T. Stanley Cameron Christine Chan |
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| Affiliation: | School of Chemistry, University of Hyderabad, Hyderabad. India;Department of Chemistry, Dalhousie University, Halifax, Canada |
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| Abstract: | A serendipitious cationic rearrangement of hexacyclic propellane to its strained fluxional isomer, the bridged 1,3,5-cyclooctatriene is described. |
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