Complete asymmetric induction in heteroconjugate addition on an acyclic system a new synthetic approach directed toward ansamacrolide maytansine |
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Authors: | Minoru Isobe Masato Kitamura Toshio Goto |
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Affiliation: | Laboratory of Organic Chemistry, Faculty of Agriculture, Nagoya University, Chikusa, Nagoya 464, Japan |
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Abstract: | Acyclic asymmetric induction was achieved in >99 % formation via coordinated intermediate () in the heteroconjugate addition ( to ); the heteroatom in the adduct being used for elongation of the carbon chain toward maytansine ). |
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