Stereoselective synthesis of β-hydroxy-α-methylketones via - and -vinyloxyboranes generated directly from cyclohexyl ethyl ketone |
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Authors: | David E. Van Horn Satoru Masamune |
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Affiliation: | Department of Chemistry, Massachusetts Institute of Technology Cambridge, Massachusetts 02139 U.S.A. |
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Abstract: | - and -dialkylvinyloxyboranes, prepared directly from cyclohexyl ethyl ketone, undergo stereo-selective aldol condensations to provide - -β-hydroxy-α-methylketones, respectively. |
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