Sensitized photooxygenation of β-methoxystyrene and 1-(β-methoxyvinyl)naphthalene |
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Authors: | Masakatsu Matsumoto Keiko Kuroda |
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Affiliation: | Sagami Chemical Research Center, Nishi-Ohnuma 4-4-1, Sagamihara, Kanagawa 229, Japan |
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Abstract: | Single oxygen can easily add to 1-(β-methoxyvinyl) naphthalene () with retention of sterochemistry to afford a stable 1,4-endoperoxide . Sensitized photooxygenation of β-methoxystyrene () gives mainly Diels-Alder adducts of -formylmethide quinone () which might be derived from initially formed 1,4-endoperoxide . |
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