Synthesis of 16-membered ring macrolide antibiotics I. Stereoselective construction of the ‘right wing” of the carbomycins and leucomycins from -glucose |
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Authors: | KC Nicolaou MR Pavia SP Seitz |
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Institution: | Department of Chemistry, University of Pennsylvania Philadelphia, PA 19104 U.S.A. |
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Abstract: | -Glucose was converted to a backbone chain containing the appropriate functionalities and correct stereochemistry for the construction of the C1–C9 fragment of the 16-membered ring macrolide antibiotics carbomycin A and B and leucomycin A3. |
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