Novel N-alkylation of a schiff base with electron-deficient olefins |
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| Authors: | Yujiro Nomura Takashi Bando Yoshito Takeuchi Shuji Tomoda |
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| Affiliation: | Department of Chemistry, College of General Education, The University of Tokyo Komaba, Meguro, Tokyo 153, Japan |
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| Abstract: | The reaction of 2,3,4,5-tetrahydropyridine with electron-deficient olefins such as methyl acrylate, acrylonitrile, and N-phenylmaleimide, provided 1-(2-methoxycarbonylethyl)-5-[1- (2-methoxycarbonylethyl)-2-piperidyl]-1,2,3,4-tetrahydropyridine, 1-(2-cyanoethyl)-5-[1-(2-cyanoethyl)-2-piperidyl]-1,2,3,4-tetrahydropyridine, and 2-(2-methoxypiperidino)-N-phenylsuccinimide, respectively, in high yields. |
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