Synthesis of β--mannopyranosides and regioselective -alkylation of dibutylstannylene complexes |
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Authors: | Vinai K Srivastava Conrad Schuerch |
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Institution: | Department of Chemistry SUNY College of Environmental Science and Forestry Syracuse, New York, 13210, USA |
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Abstract: | Alkylation of dibutylstannylene complexes of 3,4,6-tri--benzyl--mannopyranose, methyl 6--trityl-α--mannopyranoside and methyl α--mannopyranoside gives respectively β--mannopyranoside and 3--alkyl derivatives with high selectivity. |
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