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The in situ generation of Ph3P=C(CF3)2. a facile one pot conversion of aldehydes to bis-trifluoromethyl olefins. |
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| Authors: | Donald J Burton Yoshio Inouye |
| Institution: | Department of Chemistry, University of Iowa, Iowa City, Iowa 52240, U.S.A. |
| Abstract: | The in situ reaction of triphenylphosphine with tetrakis(trifluoromethyl)-1,3-dithietane in the presence of aliphatic or aromatic aldehydes gives good to excellent yields of bis-trifluoromethyl olefins. |
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