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Differential hydrogen exchange during the biosynthesis of fatty acids in Anacystisnidulans: the incorporation of [2,2,2-2H3, 2-13Co;1] acetate
Authors:A Gavin McInnes  John A Walter  Jeffrey LC Wright
Institution:National Research Council of Canada, Atlantic Regional Laboratory, 1411 Oxford Street, Halifax, Nova Scotia, Canada, B3H 3Z1
Abstract:13C NMR studies (with simultaneous1H, 2H-decoupling) of 13C, 2H-labelled methyl palmitate showed a gradation of 2H-retention along the acyl chain. The results are rationalized within the known steps of fatty acid biosynthesis.
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