|
|||||
|
|
Internal rotation and pyramidal inversion in triacylphosphines |
|
| Authors: | Dennis A. Dougherty Kurt Mislow Myung-Hwan Whangbo |
| Affiliation: | Department of Chemistry, Princeton University Princeton, New Jersey 08544 U.S.A.;Department of Chemistry, North Carolina State University Raleigh, North Carolina 27650 U.S.A. |
| Abstract: | MO calculations predict a P-C rotation barrier in triformylphosphine of less than 6 kcal/mol, and an inversion barrier of ca 14 kcal/mol. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |