Coordination compounds based on 4,6-di-tert-butyl-2-nitrosophenol |
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| Authors: | S N Lyubchenko A M Ionov I N Shcherbakov G G Aleksandrov V A Kogan A Yu Tsivadze |
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| Institution: | (1) Rostov State University, pr. Stachki 194, Rostov-on-Don, 344104, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(3) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | New metal mono-, bis-, and tris(chelates) based on 4,6-di-tert-butyl-2-nitrosophenol were synthesized and their physicochemical properties were studied. Conclusions concerning the structures of the complexes and the influence of the nature of the complexing metal on the electronic structure of the coordinated ligand were drawn from X-ray diffraction, 1H NMR, magnetochemical, and electronic spectroscopy data. |
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