Boronated enynes as versatile sources of stereodefined and skeletally diverse molecules |
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| Authors: | Hercouet Alain Berrée Fabienne Lin Chia Hui Toupet Loïc Carboni Bertrand |
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| Affiliation: | Ingéniérie Chimique et Molécules pour le Vivant, Sciences Chimiques de Rennes, UMR 6226, Rennes CEDEX, France. |
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| Abstract: | [reaction: see text] The application of a one-pot palladium-catalyzed cycloisomerization of enynes 1/Diels-Alder cycloaddition/allylboration sequence efficiently generates tricyclic structures with complete control of the four stereogenic centers. Ruthenium and platinum catalysts perform distinct transformations providing other isomeric boron-substituted cyclic compounds. |
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