Cycloaddition of fluorinated oxazoles |
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| Authors: | N V Vasil'ev V M Koshelev D V Romanov K A Lyssenko M Yu Antipin G V Zatonskii |
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| Institution: | (1) Military University of Radiation, Chemical, and Biological Defense, 13 Brigadirskii per., 107005 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(3) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | Cycloaddition reactions of polyfluorinated 1,3-oxazoles with cyclic and acyclic alkenes were studied. The results of these
reactions were interpreted using quantum chemical calculations. An unusual product, viz., fluorine-containing acylpyrrole, was studied by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1630–1635, July, 2005. |
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| Keywords: | oxazole cycloadduct hydroxypyridine acylpyrrole |
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