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Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide
引用本文:Mao Jianmin,Hou Zijie,Liu Xingping and Li Yulin(Institute of Organic Chemistry,Lanzhou University,Lanzhou). Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide[J]. 高等学校化学研究, 1988, 0(4)
作者姓名:Mao Jianmin  Hou Zijie  Liu Xingping and Li Yulin(Institute of Organic Chemistry  Lanzhou University  Lanzhou)
作者单位:Institute of Organic Chemistry,Lanzhou University,Lanzhou
基金项目:Project Supported by National Science Foundation.
摘    要:(4R,5S)-2,2-Dimethyl-4-(1',2'-dimethylpropyl)-5-(1'-bromoethyl)--1,3-dioxolane(15) with the side chain of brassinolide and (4R, 5S)--2, 2-dimethyl-4-(l'-methylene-2'-methylpropyl)-5-(1'-bromoethyl) 1,3-dioxolane(14) with the side chain of dolicholide were first synthesized through 11 and 10 stepes from D-mannitol respectively. All of the intermediates 7-13 were first synthesized too.


Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide
Mao Jianmin,Hou Zijie,Liu Xingping and Li Yulin. Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide[J]. Chemical Research in Chinese University, 1988, 0(4)
Authors:Mao Jianmin  Hou Zijie  Liu Xingping  Li Yulin
Abstract:(4R,5S)-2,2-Dimethyl-4-(1',2'-dimethylpropyl)-5-(1'-bromoethyl)--1,3-dioxolane(15) with the side chain of brassinolide and (4R, 5S)--2, 2-dimethyl-4-(l'-methylene-2'-methylpropyl)-5-(1'-bromoethyl) 1,3-dioxolane(14) with the side chain of dolicholide were first synthesized through 11 and 10 stepes from D-mannitol respectively. All of the intermediates 7-13 were first synthesized too.
Keywords:Brassinolide   Dolicholide   Side chain
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