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分子设计在热塑性弹性体制备中的应用
引用本文:崔巍,张宝森,闫卫东.分子设计在热塑性弹性体制备中的应用[J].高分子通报,2005(5):92-99.
作者姓名:崔巍  张宝森  闫卫东
作者单位:[1]河北工业大学化工学院,高分子科学与工程研究所,天津 300130 [2]中国石油天然气股份有限公司,大港石化分公司,天津 大港 300280
摘    要:本文综述了近年来基于分子设计原理制备的热塑性弹性体的研究报道,包括提高聚氨酯热塑性弹性热稳定性和柔韧性;用立构可控茂金属催化剂制备聚丙烯热塑性弹性体;热可逆共价交联聚合物和星型结构、棕榈树结构、哑铃形结构聚合物的研究.同时对乳液互穿网络型热塑性弹性体以及热塑性弹性体共混物进行了简要介绍.

关 键 词:热塑性弹性体  分子设计  星型共聚物

The Application of Molecular Design in The Preparation of Thermoplastic Elastomers
CUI Wei, ZHANG Bao-sen, YAN Wei-dong.The Application of Molecular Design in The Preparation of Thermoplastic Elastomers[J].Polymer Bulletin,2005(5):92-99.
Authors:CUI Wei  ZHANG Bao-sen  YAN Wei-dong
Institution:1.Institute of Polymer Science and Engineering, Hebei University of Technology Tianjin 300130, China ; 2.Dagang Petrochemical Corporation, Petro China Company Limited, Dagang Tianjin 300280, China
Abstract:A new generation of thermoplastic elastomers based on molecular design was introduced in this review, such as polyurethane, star block copolymer, Palm-like polymer, Dumbbell-like polymer, Latex interpenetrating polymer and grafted bends. In comparison to typical preparation, molecular design is more tightly connect to requirements in areas applied. The studies reveal these polymers exhibited improved mechanical and thermal properties.
Keywords:Thermoplastic elastomer  Molecular design  Star block copolymer
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