Assignment of the lowest triplet state of benzene using phosphorescence-microwave double resonance (PMDR) techniques |
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| Authors: | A.A. Gwaiz M.A. El-Sayed |
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| Affiliation: | Chemistry Department1, University of California, Los Angeles, California 90024, USA; Chemistry Department, University of California, Davis, California 95616, USA |
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| Abstract: | Phosphorescence-microwave double resonance (PMDR) techniques are used and the zero-field (zf) origin of the 0, 0 band of the phosphorescence of benzene-h6 in benzene-d6 at 1.6°K is determined to be the τy level. This is consistent with a 3B1u assignment for a distorted D2h benzene in its triplet state and contradicts a recently suggested 3B2u assignment. |
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