Dissociation energy of the NH3 · Hg(P0) complex |
| |
| Authors: | CG FreemanMJ McEwan RFC ClaridgeLF Phillips |
| |
| Institution: | Chemistry Department, University of Canterbury, Christchurch, New Zealand |
| |
| Abstract: | A phase-shift method has been used to study the bimolecular and termolecular reactions of Hg(3P0) with NH3. The bimolecular and termolecular rate constants are 3.8 × 10−13 cm3 molecule−1sec−1 and 1.4 × 10−30 cm6 molecule−2sec−1, respectively. From the difference between the wavelengths of peak emission intensity for the stabilized and unstabilized Hg·NH3 complexes the dissociation energy of the complex is estimated to be 5.0 kcal mole−1. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
