Light emission from gamma-irradiated alkane glasses containing olefins |
| |
| Authors: | B BrocklehurstJS Robinson |
| |
| Institution: | Department of Chemistry, The University, Sheffield S3 7HF, UK |
| |
| Abstract: | After gamma-radiolysis at 77°K, glassy alkanes emit weakly in the visible on warning. The similar but stronger emission from dilute olefin solutions suggests that the alkane luminescence is due to radiolysis products. The nature of the emitters is discussed: it is concluded tentatively that they are olefins in twisted excited states formed by recombination of olefin cations. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
