Synthesis and characterization of an iron(II) eta(2)-hydrazine complex |
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| Authors: | Crossland Justin L Zakharov Lev N Tyler David R |
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| Affiliation: | Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA. |
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| Abstract: | The iron phosphine complex cis-[Fe(DMeOPrPE)2(eta2-N2H4)][BPh4]2 {DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane} was synthesized and structurally characterized. The structure exhibits the first eta2 coordination of hydrazine to iron, which may be relevant to intermediates trapped during nitrogenase turnover. The reaction of I with acid results in the formation of ammonia via a disproportionation reaction. |
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