One-pot consecutive reactions based on the synthesis of conjugated enones by the re-catalysed meyer-schuster rearrangement |
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Authors: | Elio Mattia Alessio Porta Valentina Merlini Giuseppe Zanoni Giovanni Vidari |
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Affiliation: | Dipartimento di Chimica, Università di Pavia, Via Taramelli 12, 27100 Pavia (Italy). |
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Abstract: | Re catalysis in one-pot reactions: An atom-economical, one-pot strategy that involves alkyne deprotonation and a subsequent rhenium(V)-catalysed Meyer-Schuster rearrangement of the alkynol to provide α,?-unsaturated enones in high yield has been developed. Subsequent in situ hydride reduction or Diels-Alder reaction of the enones provided products in good-to-high overall yields. |
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