Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids |
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| Authors: | Setsune Jun-ichiro Toda Masayuki Yoshida Takafumi |
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| Institution: | Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, 657-8501 Kobe, Japan. setsunej@kobe-u.ac.jp |
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| Abstract: | Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity. |
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