Kinetic studies of unsteady-state oxidative dehydrogenation of n-butylenes over oxide catalysts |
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| Authors: | V. Yu. Mashkin L. A. Petrov D. R. Filkova A. A. Ivanov D. M. Shopov |
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| Affiliation: | (1) Institute of Catalysis, Novosibirsk, USSR;(2) Institute of Organic Chemistry, Sofia, Bulgaria |
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| Abstract: | Kinetic studies of unsteady- and steady-state oxidative dehydrogenation of n-butylenes indicate that in unsteady-state conditions the diffusion of oxygen ions out of the catalyst bulk plays a significant part. The parameters of the unsteady-state kinetic model have been numerically calculated.
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