Ambient temperature, tandem catalytic dehydrocoupling-hydrogenation reactions using Rh colloids and Me2NH.BH3 as a stoichiometric H2 source |
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| Authors: | Jaska Cory A Manners Ian |
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| Institution: | Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6. |
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| Abstract: | Highly active Rh colloids, generated in situ during the catalytic dehydrocoupling of Me2NH.BH3 using {Rh(cod)(mu-Cl)}2] as a precatalyst, are capable of efficiently hydrogenating alkenes at 25 degrees C in a one-pot procedure using only the evolved H2 from the initial dehydrocoupling reaction. |
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