Chemical Kinetics Database and Predictive Schemes for Humid Air Plasma Chemistry. Part I: Positive Ion–Molecule Reactions |
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| Authors: | Sieck L Wayne Heron John T Green David S |
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| Institution: | (1) Chemical Science and Technology Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland, 20899-0001 |
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| Abstract: | Reliable kinetic and thermodynamic data are required to model the evolution of electric discharge or electron-beam decomposition chemistry of gases in humid air streams. In this first segment of a continuing series, we provide a core database describing the initially dominant ion-neutral molecule reactions in humid air plasmas. Recommended reaction rate data and extrapolation tools are presented in a manner to facilitate prediction of reactivities and reaction channels as a function of temperature, pressure, and applied electric field. |
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| Keywords: | plasma discharge electron beam database ion molecule kinetic thermodynamic rate constant humid air |
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