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Catalytic asymmetric Friedel-Crafts/protonation of nitroalkenes and N-heteroaromatics
Authors:Arai Takayoshi  Awata Atsuko  Wasai Makiko  Yokoyama Naota  Masu Hyuma
Institution:Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan. tarai@faculty.chiba-u.jp
Abstract:The catalytic asymmetric Friedel-Crafts/protonation of indoles and pyrroles with α-substituted nitroalkenes to give the corresponding adducts in a highly anti-selective manner was achieved by an imidazoline-aminophenol (L2)-Cu complex. The anti-adducts could be successfully transformed to biochemically important α-substituted β-heteroarylalkylamines.
Keywords:
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