Samarium(II)-mediated linker cleavage-cyclization in fluorous synthesis: reactions of samarium enolates |
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| Authors: | James Karen M Willetts Nigel Procter David J |
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| Institution: | The School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK. |
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| Abstract: | SmI2 has been used to cleave a sulfur linker and trigger cyclizations in strategies for the traceless fluorous synthesis of N-heterocycles. The studies give further insights into the reactivity of samarium enolates. |
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