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Studies on 1H NMR, infrared and fluorescence spectra of rare earth complexes with a new binaphthylamide
Authors:Wang Ya-Wen  Liu Wei-Sheng  Tang Ning  Tan Min-Yu
Affiliation:Department of Chemistry and National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Abstract:Solid complexes of lanthanide picrates with N,N-dibenzyl-2-[2'-[(dibenzylcarbamoyl)-methoxy]-[1,1']binaphthalenyl-2-yloxy]-acetamide (L), [Ln(pic)(3)L] (Ln = La, Nd, Eu, Gd, Tb, Dy, Y), have been prepared and characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in CHCl(3), acetone, AcOEt and DMF was studied.
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