| Improved Electrochemical Synthesis of Nitro-substituted 1-Aryl-2-pyrrolidinecarbonitriles |
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| 作者姓名： | Wei LIU Yuan MA Ying Wu YIN Yu Fen ZHAO |
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| 作者单位： | [1]The Key Laboratory for Bioorganic Phosphorus Chemistry ＆ Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084 [2]Department of Chemistry, Tsinghua University,Beijing 100084 [3]Beijing TH-UNIS Insight Co.Ltd., Beijing 100084 |
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| 基金项目： | 科技部资助项目;中国科学院资助项目;清华大学校科研和教改项目 |
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| 摘 要： | Anodic cyanation is expected to provide a promising method for synthesis of nitriles by reason of its positional reactivity and simple operation1. Within our ongoing interest in cyano group incorporation into small heterocyclic ring systems2, 3, the elect…
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| 关 键 词： | 阳极氰化作用 腈 硝基取代 1-芳基-2-吡咯烷腈 电化学合成 |
| 收稿时间： | 2005-12-19 |
Improved Electrochemical Synthesis of Nitro-substituted 1-Aryl-2-pyrrolidinecarbonitriles |
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| Wei LIU Yuan MA Ying Wu YIN Yu Fen ZHAO.Improved Electrochemical Synthesis of Nitro-substituted 1-Aryl-2-pyrrolidinecarbonitriles[J].Chinese Chemical Letters,2006,17(6):736-738. |
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| Authors: | Wei LIU Yuan MA Ying Wu YIN Yu Fen ZHAO |
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| Abstract: | In this paper, we described an improved electrochemical method for synthesis of some 1-aryl-2-pyrrolidinecarbonitrile derivatives bearing an electron-withdrawing group (NO2). The electrochemical synthesis of titile compounds has been successfully performed in an undivided cell in reasonable yields. |
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| Keywords: | Anodic cyanation nitrile pyrrolidine electrochemistry |
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