| Structure and Luminescence Property of a Linear Tetranuclear Gold(Ⅰ)-thiolate Complex through Au-Au Interaction |
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| 引用本文： | 江峰,李佳,陈忠宁.Structure and Luminescence Property of a Linear Tetranuclear Gold(Ⅰ)-thiolate Complex through Au-Au Interaction[J].结构化学,2014,33(5):741-745. |
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| 作者姓名： | 江峰 李佳 陈忠宁 |
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| 作者单位： | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences |
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| 基金项目： | financial supports from the NNSFC（20931006,U0934003,and 91122006）; the NSF of Fujian Province（2011J01065） |
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| 摘 要： | The synthesis,structure and luminescent property of a tetranuclear gold(Ⅰ)complex with doubly bridging diethyldithiocarbamate(Et2dtc)and 1,1-bis(diphenylphosphino)ethene((Ph2P)2C=CH2)are described.The complex crystallizes in monoclinic space group C2/c with a=26.785(7),b=25.654(6),c=12.277(3)A,β=106.879(5)°,V=8073(4)A~3,Z=8,C31H32Au2F6NO3P2S2Sb,Mr=1222.32,Dc=2.011 g/cm~3,F(000)=4592,Rint=0.0529,T=293(2)K,μ=8.157 mm~(-1),the final R=0.0464 and wR=0.1444 for 5804 observed reflections with I2σ(Ⅰ).The intramolecular and intermolecular Au¨Au distances are 2.8670(9)and 3.2367(9)A,respectively.Weak emission appears at 517 nm at room temperature in the solid state.
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| 关 键 词： | gold(Ⅰ) complex crystal structure luminescence property |
Structure and Luminescence Property of a Linear Tetranuclear Gold（Ⅰ）-thiolate Complex through Au-Au Interaction |
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| JIANG Feng
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LI Jia
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CHEN Zhong-Ning.Structure and Luminescence Property of a Linear Tetranuclear Gold（Ⅰ）-thiolate Complex through Au-Au Interaction[J].Chinese Journal of Structural Chemistry,2014,33(5):741-745. |
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| Authors: | JIANG Feng LI Jia CHEN Zhong-Ning |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China |
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| Abstract: | gold（Ⅰ） complex crystal structure luminescence property |
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| Keywords: | gold（Ⅰ） complex crystal structure luminescence property |
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