The leaching of Rhodamine B, Naphthol Blue Black, Metanil Yellow and Bismarck Brown R from silica deposits on polyester and viscose textiles |
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Authors: | T Nedel?ev I Krupa D Lath M ?pírková |
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Institution: | (1) Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 842 36 Bratislava, Slovakia;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovského nám. 2, 162 06 Praha 6, Czech Republic |
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Abstract: | Rhodamine B (RB), Naphthol Blue Black (NBB), Metanil Yellow (MTY) and Bismarck Brown R (BHR) immobilized within a modified silica sol were used for the surface dyeing of textiles, namely polyester and viscose
fabrics. Silica sols were characterized by FTIR and dynamic light-scattering measurements. The sol was dip-coated onto the
fabrics and deposits were formed. Three similar procedures for the formation of silica deposits, using tetraethoxysilane (TEOS)
and (3-glycidoxypropyl)trimethoxysilane (GPTMS) as precursors in acidified ethanol, were tested. Interactions between dyes
and silica precursors were investigated by FTIR measurements. Leaching was detected and quantified by UV–Vis measurements
on the composition of washing solutions. Incorporation of GPTMS into silica sols reduces dye leaching from the silica deposits. |
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Keywords: | Sol– gel process Textile Polyester Viscose Surface dyeing Immobilization |
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