LiNaSO4-MgSO4赝二元系中离子导体的研究

本文用差热分析和X射线衍射方法,对LiNaSO₄-MgSO₄赝二元系相图进行了研究。在此体系中存在三个化合物,它们分别为(LiNa)_0.8Mg(0.2)SO₄,(LiNa)_0.67Mg_0.33SO₄和(LiNa)_0.4Mg_0.6SO₄。研究了三种化合物的离子导电性,在490℃时上述三个化合 关键词：

STUDY ON IONIC CONDUCTORS IN PSEUDO-BINARY SYSTEM LiNaSO4-MgS04

The phase diagram of pseudo-binary system LiNaS0₄-MgSO₄ system has been studied by means of DTA and X-ray diffraction technique. Three compounds (LiNa)_0.8Mg_{0.20.8·Mg0.2 SO4 (LiNa)0.67Mg0.33 SO4 and (LiNa)0.4 Mg0.6 SO4 have been found in this system.The ionic conductions in these three compounds have been investigated. The ionic conductivities at 490℃ are 6.1×10^-5S ·cm^-1, 6.5×10^-5S·cm^-1 and 9.8×10^-6S·cm^-1 with activa tion energies 1.67 eV, 1.48 eV and 1.32 eV, respectively. The prototype high temperature thermal batteries Mg/MnO2 using these compounds respectively as electrolyte have been made and tested. The results show that, Mg/ (LiNa)0.8Mg0.2 SO4/MnO2 cell has better Polarization and discharg behaviour than the others. Hence (LiNa)0.8Mg0.2SO4 might be used as electrolyte in high temperature thermal battery.}